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Hydrogen solubility of stishovite provides insights into water transportation to the deep Earth.

Authors :
Chen, Mengdan
Yin, Changxin
Chen, Danling
Tian, Long
Liu, Liang
Kang, Lei
Source :
Solid Earth; 2024, Vol. 15 Issue 2, p215-227, 13p
Publication Year :
2024

Abstract

Water dissolved in nominally anhydrous minerals (NAMs) can be transported to deep regions of the Earth through subducting slabs, thereby significantly influencing the physicochemical properties of deep-Earth materials and impacting dynamic processes in the deep Earth. Stishovite, a prominent mineral present in subducting slabs, remains stable at mantle pressures of 9–50 GPa and can incorporate various amounts of water (H + , OH - , and H 2 O) in its crystal structure. Consequently, stishovite can play a crucial role in transporting water into the deep Earth through subducting slabs. This paper provides a comprehensive review of the research process concerning water (hydrogen) solubility in stishovite. The key factors that govern water solubility in stishovite are summarized as temperature, pressure, water fugacity, and aluminum content. Combined with published results on the dependence of water solubility on the aforementioned parameters, this paper proposes a new equation to describe the solubility of water in Al-bearing stishovite. Calculation results based on this equation suggest that stishovite may effectively accommodate water released from processes such as hydrous mineral breakdown, which could ultimately contribute to the presence of a water-rich transition zone. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
18699510
Volume :
15
Issue :
2
Database :
Complementary Index
Journal :
Solid Earth
Publication Type :
Academic Journal
Accession number :
176252303
Full Text :
https://doi.org/10.5194/se-15-215-2024