Exploring the effect of dynamic bond placement in liquid crystal elastomers.

Dynamic liquid crystal elastomers (LCEs) are a class of polymer networks characterized by the inclusion of both liquid crystalline monomers and dynamic covalent bonds. The unique properties realized through the combination of these moieties has produced a plethora of stimuli‐responsive materials to address a range of emerging technologies. While previous works have studied the incorporation of different dynamic bonds in LCEs, few (if any) have studied the effect of the specific placement of the dynamic bonds within an LCE network. A series of dynamic LCE networks were synthesized using a generalizable approach that employs a tandem thiol‐ene/yne chemistry which allows the location of the dynamic disulfide bond to be varied while maintaining similar network characteristics. When probing these systems in the LC regime, the thermomechanical properties were found to be largely similar. It is not until elevated temperatures (160–180 °C) that differences in the relaxation activation energies of these systems begin to materialize based solely on differences in placement of the dynamic bond throughout the network. This work demonstrates that through intentional dynamic bond placement, stress relaxation times can be tuned without affecting the LCE character. This insight can help optimize future dynamic LCE designs and achieve shorter processing times. [ABSTRACT FROM AUTHOR]