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Negative diffusion of excitons in quasi-two-dimensional systems.

Authors :
Kurilovich, Aleksandr A.
Mantsevich, Vladimir N.
Chechkin, Aleksei V.
Palyulin, Vladimir V.
Source :
Physical Chemistry Chemical Physics (PCCP); 1/14/2024, Vol. 26 Issue 2, p922-935, 14p
Publication Year :
2024

Abstract

We show how two different mobile-immobile type models explain the observation of negative diffusion of excitons reported in experimental studies in quasi-two-dimensional semiconductor systems. The main reason for the effect is the initial trapping and a delayed release of free excitons in the area close to the original excitation spot. The density of trapped excitons is not registered experimentally. Hence, the signal from the free excitons alone includes the delayed release of not diffusing trapped particles. This is seen as the narrowing of the exciton density profile or decrease of mean-squared displacement which is then interpreted as a negative diffusion. The effect is enhanced with the increase of recombination intensity as well as the rate of the exciton–exciton binary interactions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14639076
Volume :
26
Issue :
2
Database :
Complementary Index
Journal :
Physical Chemistry Chemical Physics (PCCP)
Publication Type :
Academic Journal
Accession number :
174575785
Full Text :
https://doi.org/10.1039/d3cp03521b