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Solubilities of Components in the Сa(ClO3)2∙NH4Сl–H2O System.

Authors :
Rakhmonov, O. O.
Sidikov, A. A.
Shukurov, Zh. S.
Togasharov, A. S.
Source :
Russian Journal of Inorganic Chemistry; Dec2023, Vol. 68 Issue 12, p1829-1833, 5p
Publication Year :
2023

Abstract

The Сa(ClO<subscript>3</subscript>)<subscript>2</subscript>∙NH<subscript>4</subscript>Сl–H<subscript>2</subscript>O system has been studied in its constituent binary systems and seven inner sections, and its polythermal solubility diagram has been plotted in the range of temperatures from–42.5 to 87.5°С. The solubility diagram features the crystallization fields of ice; calcium chlorate hexahydrate, tetrahydrate, and dihydrate; and ammonium chloride. Three ternary points exist in the system. The system belongs to the complex eutonic type; its components retain their individuality and show good solubility in water. In the [40% Сa(ClO<subscript>3</subscript>)<subscript>2</subscript> + 60% H<subscript>2</subscript>O]–[NH<subscript>4</subscript>Сl] section of the studied system, variations in crystallization temperature, viscosity, density, pH, and refractive indices of the solution have been determined. The thus-obtained results have been used to plot the composition–property diagram of the [40% Сa(ClO<subscript>3</subscript>)<subscript>2</subscript> + 60% H<subscript>2</subscript>O]–[NH<subscript>4</subscript>Сl] section of the Сa(ClO<subscript>3</subscript>)<subscript>2</subscript>∙NH<subscript>4</subscript>Сl–H<subscript>2</subscript>O system. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00360236
Volume :
68
Issue :
12
Database :
Complementary Index
Journal :
Russian Journal of Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
174495563
Full Text :
https://doi.org/10.1134/S0036023623602271