Hybrid Filtration Process for Gas Desulfurization.

A hybrid desulfurization process combining a physical filtration stage on cellular concrete (CC abiotic filter, called CCAF) and a biotrickling filter (called BTF) filled with expanded schist as packing material was used to remove high H₂S concentrations from a synthetic gas containing dinitrogen (N₂), dioxygen (O₂) and H₂S without the addition of a nutritive solution. Provided that small amounts of oxygen are present in the gas (1.2 ± 0.1% in volume), the global removal efficiency was 100%, and the global removal capacity reached 35 ± 2 gH₂S m⁻³ h⁻¹ for a total empty bed residence time (EBRT) of 120 s (CCAF + BTF). The resilience of the desulfurization process was demonstrated by applying severe changes in the H₂S concentrations, from 160 to 1150 ± 20 mg m⁻³ for an EBRT = 120 s. According to the performances of the abiotic filter, which can decline over time due to the lifetime of the cellular concrete (137 days), the biotrickling filter reacted either as a refining system or as an efficient system able to treat significant H₂S loading rates (up to 45 ± 3 gH₂S m⁻³ h⁻¹). Depending on the operating conditions, the increase in the pressure drops of the biotrickling filter (from 45 ± 3 to 234 ± 8 Pa m⁻¹) highlighted biomass accumulation, especially extremophilic Acidithiobacillus sp. Considering the cellular concrete abiotic filter alone, removal capacities of up to 56 ± 3 gH₂S m⁻³ h⁻¹ were recorded for an EBRT of 60 s, demonstrating that gases such as landfill biogas or household biogas could be efficiently treated using this simple technique. [ABSTRACT FROM AUTHOR]