A Co(TAML)-based artificial metalloenzyme for asymmetric radical-type oxygen atom transfer catalysis.

Authors :: Meeus, Eva J.
Igareta, Nico V.
Morita, Iori
Ward, Thomas R.
de Bruin, Bas
Reek, Joost N. H.
Source :: Chemical Communications; 12/21/2023, Vol. 59 Issue 98, p14567-14570, 4p
Publication Year :: 2023
Abstract: We show that the incorporation of a biotinylated Co(TAML) cofactor within streptavidin enables asymmetric radical-type oxygen atom transfer catalysis with improved activity and enantioselectivity. [ABSTRACT FROM AUTHOR]

Subjects :: CATALYTIC activity
CATALYSIS
ATOMS
OXYGEN
PHASE-transfer catalysis
STREPTAVIDIN

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