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High-pressure induced guest-mediated gate opening behaviour of the Co-based framework ZIF-67.
- Source :
- CrystEngComm; 12/21/2023, Vol. 25 Issue 47, p6533-6538, 6p
- Publication Year :
- 2023
-
Abstract
- High-pressure single crystal X-ray diffraction has been used to probe framework–guest interactions in the Co-based metal–organic framework ZIF-67 during compression in 4 : 1 MeOH : EtOH and liquid nitrogen (LN<subscript>2</subscript>) pressure-transmitting media. On increasing pressure, the structure undergoes a gate-opening phase transition, characterised by rotation of the 2-methylimidazolate ligand, at 1.57 GPa in MeOH : EtOH and at 0.43 GPa LN<subscript>2</subscript>. Adsorption of N<subscript>2</subscript> occurred progressively with increasing pressure into 6 adsorption sites and resulted in the first documented instance of pressure-induced solvatochromism in ZIF-67. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 25
- Issue :
- 47
- Database :
- Complementary Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 173968749
- Full Text :
- https://doi.org/10.1039/d3ce00979c