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Benz[e]indenyl and benz[f]indenyl molybdenum compounds: evidence of the η3-coordination mode.
- Source :
- New Journal of Chemistry; 12/14/2023, Vol. 47 Issue 46, p21396-21403, 8p
- Publication Year :
- 2023
-
Abstract
- This study reports the synthesis and characterization of new molybdenum compounds bearing benz[e]indenyl and benz[f]indenyl ligands. The capability of the ligands to undergo η<superscript>5</superscript>-to-η<superscript>3</superscript> haptotropic rearrangement was evidenced on reactions with tris(pyrazolyl)methane. Appearance of the η<superscript>3</superscript>-coordination mode was determined by NMR spectroscopy and X-ray structure analysis on a single crystal. [ABSTRACT FROM AUTHOR]
- Subjects :
- X-ray spectroscopy
SINGLE crystals
MOLYBDENUM compounds
LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 47
- Issue :
- 46
- Database :
- Complementary Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 173860914
- Full Text :
- https://doi.org/10.1039/d3nj04406h