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The Functionalization of PES/SAPO-34 Mixed Matrix Membrane with [emim][Tf 2 N] Ionic Liquid to Improve CO 2 /N 2 Separation Properties.
- Source :
- Inorganics; Nov2023, Vol. 11 Issue 11, p447, 16p
- Publication Year :
- 2023
-
Abstract
- The use of ionic liquid [emim][Tf<subscript>2</subscript>N] as an additive in polyethersulphone (PES) and nano-sized silico-aluminophosphate-34 (SAPO-34) mixed matrix membrane was studied through the incorporation of different amounts of [emim][Tf<subscript>2</subscript>N] in the membrane composition, as presented in this work, varying from 10 to 40 wt%. Through gas permeation tests using CO<subscript>2</subscript> and N<subscript>2</subscript>, the membrane composition containing 20 wt% [emim][Tf<subscript>2</subscript>N] led to the highest increase in CO<subscript>2</subscript> permeability and CO<subscript>2</subscript>/N<subscript>2</subscript> selectivity. The use of low concentrations of additive (10–20 wt%) promoted a state called antiplasticization; in this state, the permeability was even more regulated by the kinetic diameter of the species which, in this work, permitted achieving a higher CO<subscript>2</subscript>/N<subscript>2</subscript> selectivity while increasing the CO<subscript>2</subscript> permeability until an optimal condition. [emim][Tf<subscript>2</subscript>N] also promoted a better dispersion of SAPO-34 particles and an increase in the flexibility of the polymeric matrix when compared to a film with the same composition without [emim][Tf<subscript>2</subscript>N]. Moreover, the characterizations corroborated that the inclusion of [emim][Tf<subscript>2</subscript>N] increased the zeolite dispersion and improved the polymer/zeolite compatibility and membrane flexibility, characterized by a decrease in glass transition temperature, which helped in the fabrication process while presenting a similar thermal resistance and hydrophilicity as neat PES membrane, without affecting the membrane structure, as indicated by FTIR and a contact angle analysis. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 23046740
- Volume :
- 11
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Inorganics
- Publication Type :
- Academic Journal
- Accession number :
- 173829766
- Full Text :
- https://doi.org/10.3390/inorganics11110447