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Direct Arylation Polycondensation of Thiophene-Based C-H Monomers.
- Source :
- Chinese Journal of Chemistry; Nov2023, Vol. 41 Issue 21, p2908-2924, 17p
- Publication Year :
- 2023
-
Abstract
- Direct arylation polycondensation (DArP) has emerged as an eco-friendly and atom-efficient methodology for the syntheses of π-conjugated polymers (CPs). This approach features the direct C-H arylation of an aromatic hydrocarbon with an aryl halide. Given the prevalence of thiophene-containing CPs, achieving efficient and defect-free DArP of thiophene-based C-H monomers is of great significance. This review presents a mechanistic insight into DArP and describes the development of DArP catalytic systems for varied thiophene-based C-H monomers. Moreover, the control of the primary defects (i.e., branching and homo-coupling) in thiophene-based DArP is also elaborated. By emphasizing the principles behind monomer selection and catalytic system optimization, this review intends to provide a framework for future advancements in the DArP of thiophene-containing CPs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 41
- Issue :
- 21
- Database :
- Complementary Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 173708664
- Full Text :
- https://doi.org/10.1002/cjoc.202300194