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Ga+-catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions.

Ga+-catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions.

Authors :
Barthélemy, Antoine
Glootz, Kim
Scherer, Harald
Hanske, Annaleah
Krossing, Ingo
Source :
Chemical Science; 1/14/2022, Vol. 13 Issue 2, p439-453, 15p
Publication Year :
2022

Details

Language :
English
ISSN :
20416520
Volume :
13
Issue :
2
Database :
Complementary Index
Journal :
Chemical Science
Publication Type :
Academic Journal
Accession number :
173590397
Full Text :
https://doi.org/10.1039/d1sc05331k