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Terpolymers of acrylonitrile, methyl acrylate, and 2-acrylamido-2-methylpropane sulfonic acid for carbon fiber precursor: Effect of comonomers on the thermal stabilization of polyacrylonitrile copolymers.

Authors :
Qiufei Chen
Bin He
Yatian Chen
Hongqiang Zhu
Malik, Hamza
Yuhang Wang
Jian He
Bomou Ma
Xueli Wang
Hui Zhang
Yong Liu
Source :
Journal of Applied Polymer Science; 11/10/2023, Vol. 140 Issue 42, p1-13, 13p
Publication Year :
2023

Abstract

Polyacrylonitrile (PAN) copolymers are important precursors for the preparation of high-performance PAN-based carbon fibers. In this study, different ratios of P(AN-co-AMPS) and P(AN-co-MA-co-AMPS) were prepared by solution polymerization. The compositional structure, thermal, and crystallization properties of P(AN-co-AMPS) and P(AN-co-MA-co-AMPS) were characterized. The results show that an increase in the AMPS feeding ratio is beneficial for improving the thermal stability and crystallization ability of the PAN copolymer; however, it also reduces the molecular weight of the copolymer and increases the cyclization exothermic peak temperature, which is not conducive to the preparation of high-performance carbon fibers. This problem is avoided in P(AN-co-MA-co-AMPS), which maintains its high thermal stability and crystallization properties when appropriate amounts of MA and AMPS are introduced, and P(AN-co-MA-co-AMPS) has smoother cyclization exothermic rates, lower onset exothermic temperatures and lower peak exothermic temperatures. The structural changes of PAN, P(AN-co-MA), and P(AN-co-MA-co-AMPS) during thermal stabilization were investigated in detail using Fourier-transform infrared spectroscopy and it was found that P(AN-co-MAco-AMPS) formed more stable structures at lower temperatures. Furthermore, when the AN:MA:AMPS mass ratio is 97.5:1.5:1, P(AN-co-MA-co-AMPS) has the best overall performance. Our results suggest that the P(AN-co-MA-co-AMPS) has potential as a precursor for carbon fibers. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00218995
Volume :
140
Issue :
42
Database :
Complementary Index
Journal :
Journal of Applied Polymer Science
Publication Type :
Academic Journal
Accession number :
173424437
Full Text :
https://doi.org/10.1002/app.54552