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Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy.
- Source :
- Chemical Communications; 10/28/2023, Vol. 59 Issue 84, p12609-12612, 4p
- Publication Year :
- 2023
-
Abstract
- Matere bonds (MaB) to rhenium in a set of organic perrhenates are probed via<superscript>185/187</superscript>Re solid-state NMR in applied magnetic fields of up to 35.2 T, and via<superscript>185/187</superscript>Re NQR. <superscript>185/187</superscript>Re quadrupolar couplings distinguish between MaB samples and control samples, and their precise values are governed by shear strain of the ReO<subscript>4</subscript><superscript>−</superscript> anions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 84
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 173105039
- Full Text :
- https://doi.org/10.1039/d3cc04090a