Synthesis of Liquid Hydrocarbon via Direct Hydrogenation of CO 2 over FeCu-Based Bifunctional Catalyst Derived from Layered Double Hydroxides.

Here, we report a Na-promoted FeCu-based catalyst with excellent liquid hydrocarbon selectivity and catalytic activity. The physiochemical properties of the catalysts were comprehensively characterized by various characterization techniques. The characterization results indicate that the catalytic performance of the catalysts was closely related to the nature of the metal promoters. The Na-AlFeCu possessed the highest CO₂ conversion due to enhanced CO₂ adsorption of the catalysts by the introduction of Al species. The introduction of excess Mg promoter led to a strong methanation activity of the catalyst. Mn and Ga promoters exhibited high selectivity for light hydrocarbons due to their inhibition of iron carbides generation, resulting in a lack of chain growth capacity. The Na-ZnFeCu catalyst exhibited the optimal C₅₊ yield, owing to the fact that the Zn promoter improved the catalytic activity and liquid hydrocarbon selectivity by modulating the surface CO₂ adsorption and carbide content. Carbon dioxide (CO₂) hydrogenation to liquid fuel is considered a method for the utilization and conversion of CO₂, whereas satisfactory activity and selectivity remains a challenge. This method provides a new idea for the catalytic hydrogenation of CO₂ and from there the preparation of high-value-added products. [ABSTRACT FROM AUTHOR]