Effect of type of Fe(III) salts and reaction temperature in the synthesis of Fe(III)-Mn(II)-Tartrate heteronuclear complex.

Synthesis of heteronuclear complexes of Fe(III)-Mn(II)-Tartrate is reported here. The tartrate based heteronuclear complex was developed as functional material for catalytic applications and molecular magnets. Effect of type of Fe(III) salts and reaction temperature in the solvothermal synthesis of the targeted complex is also investigated. FeCl₃ and (NH₄)Fe(SO₄)₂ were used as the source of Fe(III) salts, in which the Fe(III) salt solutions were then mixed with solutions of MnCl₂ and L−tartaric acid in a Fe(III)-Mn(II)-Tartrate mol ratio of 2:2:5 in a 50 mL of Teflon-autoclave. A mixture of dimethyl formamide and distilled water (1:3) was used as the solvent. The solvothermal reaction was done at 110 and 130 °C, respectively, for 2 hours. Solids that precipitated out from the reaction were separated by filter paper, dried in an oven, and then characterized by Fourier Transform Infrared (FTIR) spectroscopy, atomic absorption spectrophotometer (AAS), and powder XRD analysis. Experimental data shows that all four reactions resulted in identical pale yellow-greenish fine powder in different yields. FTIR analysis confirms the presence of tartrate ligand based on specific absorptions, namely a broad band around 3400 (O–H) cm⁻¹, a sharp peak around 1650 (O–C=O) cm⁻¹, and twin sharp peaks around 1400-1100 (C–OH) cm⁻¹. Moreover, AAS confirms the presence of both Fe and Mn in all samples in a considerably significant amount. Powder XRD analyses confirmed that the synthesized complexes have identical crystal system. These results indicate that complexes of Fe(III)-Mn(II)-Tartrate were formed and the synthesis of the complex were not influenced by the type of Fe(III) salts or by the reaction temperature. [ABSTRACT FROM AUTHOR]