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Carbonate Hydrogenated to Formate in the Aqueous Phase over Nickel/TiO2 Catalysts.
- Source :
- Angewandte Chemie; 10/9/2023, Vol. 135 Issue 41, p1-6, 6p
- Publication Year :
- 2023
-
Abstract
- Carbonate hydrogenation to formate is a promising route to convert captured carbon dioxide into valuable chemicals, thus reducing carbon emissions and creating a revenue return. Developing inexpensive catalysts with high activity, selectivity, and stability remains challenging. We report a supported non‐noble metal catalyst, Ni/TiO2, with great selectivity over 96 % and excellent stability in catalyzing the conversion of carbonate into formate in aqueous solution. Ni0 and Ni2+ species are both observed in Ni/TiO2 catalysts, and the synergistic effect of these two Ni components leads to high activity and high selectivity of carbonate hydrogenation to formate. [ABSTRACT FROM AUTHOR]
- Subjects :
- METAL catalysts
CATALYSTS
CARBONATES
CARBON emissions
CARBON dioxide
Subjects
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 135
- Issue :
- 41
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 172756817
- Full Text :
- https://doi.org/10.1002/ange.202307061