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Regenerative one-stage catalytic absorption process with cupric ions for removal of reduced sulfur compounds in polluted air.

Authors :
Kasper, Pernille Lund
Feilberg, Anders
Source :
Environmental Technology; Nov2023, Vol. 44 Issue 25, p3926-3936, 11p
Publication Year :
2023

Abstract

Reduced volatile sulfur compounds emitted from e.g. livestock production and biogas production facilities contribute to general air pollution and local odour nuisance. Improved technologies are required to mitigate the emissions of both hydrogen sulfide and organic sulfur compounds. The present study examines the oxidative absorption of reduced sulfur compounds, i.e. hydrogen sulfide, methanethiol and dimethyl sulfide in a wet oxidation process with cupric chloride. It was found that this process efficiently removes both hydrogen sulfide and methanethiol with removal efficiencies >94% under all process conditions tested, while the removal of dimethyl sulfide was in the range 20–40%. The main products determined were dimethyl disulfide, dimethyl trisulfide and elemental sulfur. It was shown that the process was more efficient than the similar process with ferric ions and higher removal could be obtained with lower residence times. Furthermore, though employing cupric ion as metal catalysts results in the production of gaseous sulfur compounds, it is estimated that this process is efficient for deodorization due to the higher odour threshold values of the product compounds and the pH range is optimal for gas streams containing CO<subscript>2</subscript>. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09593330
Volume :
44
Issue :
25
Database :
Complementary Index
Journal :
Environmental Technology
Publication Type :
Academic Journal
Accession number :
172441271
Full Text :
https://doi.org/10.1080/09593330.2022.2077132