Enhanced Photocatalytic Dehalogenation Performance of RuDoped In 2 O 3 Nanoparticles Induced by Oxygen Vacancy.

Due to its favorable excited-state physicochemical properties, indium oxide (In₂O₃) has widely captured attention as a potentially great photocatalyst. However, an inferior charge separation efficiency limits its application. Recently, an increasing amount of evidence has demonstrated that the construction of surface defects is an effective strategy to boost photocatalytic performances. In this work, a ruthenium (Ru) species was successfully introduced into the lattice of In₂O₃ nanoparticles through co-precipitation and thermal treatment. It was found that the content of surface oxygen vacancies was directly related to the amount of Ru³⁺ doping, which further determines the separation efficiency of photogenerated carriers. As a result, the 0.5% Ru-In₂O₃ samples enriched with oxygen vacancies exhibit dramatically enhanced photocatalytic dehalogenation performances of decabromodiphenyl ether and hexabromobenzene, about four times higher than that of the pure In₂O₃ nanoparticles. This study emphasized the significance of the surface defects of the photocatalyst and may provide a valuable strategy to prepare highly active photocatalysts for photocatalytic dehalogenation reactions. [ABSTRACT FROM AUTHOR]