Shock-to-detonation transition behavior of functionally graded energetic materials.

The behavior of energetic materials is significantly influenced by the spatial distributions of microstructure heterogeneities and voids. We pursue the concept of Functionally Graded Energetic Materials whose microstructure features (e.g., grain size, grain volume fraction, void size, and void volume fraction) change spatially such that they may allow the behavior of the materials to be tailored. We explore using gradients in the density of voids to alter the detonation behavior of a polymer-bonded explosive (PBX) echoing PBX9501 with HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) grains and Estane binder. Five cases, two graded void distributions from 1% to 10% and 10% to 1% by volume along the length of the sample, and three uniform distributions matching the lowest (1%), average (5.5%), and highest (10%) void densities are considered. An Arrhenius reaction burn model is used to account for the chemical kinetics of HMX. Different detonation behaviors are obtained from the same graded sample when impact loading is from 1% void end and from the 10% void end as well as from the uniform cases. The SDT (shock to detonation transition) behaviors are analyzed in terms of the run distance, the time duration and shock velocity changes over the SDT process. The computational results are presented in the context of available experimental data for PBX9501 with which agreement is obtained through a parametric study. Overall, it is shown that gradients in microstructures of PBX can lead to SDT behaviors different or not obtainable from microstructures without gradients, thereby offering a mechanism for designing and tailoring new materials. [ABSTRACT FROM AUTHOR]