The Influence of Casting Static Compaction Pressure on Carbonated Reactive Magnesia Cement (CRMC)-Based Mortars †.

The current study evaluates the influence of the static compaction pressure applied during the casting process on Carbonated Reactive Magnesia Cement-based mortars. For this purpose, mortars, embodying biomass fly ash as filler, were designed and moulded through static compaction pressures of 10, 30, 50, and 70 MPa. The moulded specimens were submitted to an accelerated carbonation curing period of 24 h under controlled conditions. The devised mortars were evaluated through compressive strength tests, and their microstructure was assessed through Mercury Intrusion Porosimetry (MIP), Thermogravimetry and Derivative Thermogravimetry (TG-DTG), and Fourier-transform Infrared Spectroscopy (FTIR) analyses. The results showed that the increment in the static compaction pressure during the specimens' casting process not only led the mortars to reduce their porosity by up to ~30% and increase their compressive strength by up to ~58% (from 19.8 MPa to 31.2 MPa) but also that such a change seems to hinder the CO₂ diffusion into the specimens' core, thus resulting in a lower content of carbonated products. In addition, the MIP analyses demonstrated that the static compaction pressure applied in the mortar casting process changes the pores' characteristics, while TG-DTG and FTIR analyses provided evidence that the devised mortars were carbonated to a certain degree. Therefore, this work demonstrated that Carbonated Reactive Magnesia Cement-based mortars are highly influenced by the static compaction pressure applied during the casting process, at least up to a certain value. [ABSTRACT FROM AUTHOR]