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One-step fabrication of vanadium-doped CoFe PBA nanosheets for efficient oxygen evolution reaction.

Authors :
Huang, Yin
Pan, Yaoyao
Huang, Xiaoyu
Xu, Guangzheng
Wang, Xiuhua
Source :
Dalton Transactions: An International Journal of Inorganic Chemistry; 8/28/2023, Vol. 52 Issue 32, p11297-11302, 6p
Publication Year :
2023

Abstract

Finding effective and affordable non-noble metal catalysts is one of the most important yet difficult tasks because of the sluggish kinetics of the oxygen evolution reaction (OER). Therefore, we synthesized vanadium-doped CoFe PBA nanosheets on nickel foam in a single step to change the electronic structure with metal doping. The sheet structure facilitates charge transfer, while vanadium doping modifies the electronic structure to enhance the catalytic activity. With just a 229 mV overpotential needed in the OER reaction to reach 10 mA cm<superscript>−2</superscript>, the as-synthesised electrocatalyst demonstrates high electrocatalytic activity. The produced electrocatalyst can operate at a current density of 10 mA cm<superscript>−2</superscript> for 12 h, and it displays outstanding stability even at a high OER current density of 100 mA cm<superscript>−2</superscript> for 12 h. This study will contribute to the development of efficient and affordable non-noble metal-based electrocatalysts. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14779226
Volume :
52
Issue :
32
Database :
Complementary Index
Journal :
Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
169952451
Full Text :
https://doi.org/10.1039/d3dt01629c