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Imidazole-Based Bronsted Acidic Surfactant: A Novel Regioselective Catalytic System for Making of 2-Aryl-1,2-Dihydrothiazolo[3,2-b][1, 2, 4]Triazol-6(5H)-Ones.
- Source :
- Polycyclic Aromatic Compounds; 2023, Vol. 43 Issue 7, p6484-6501, 18p
- Publication Year :
- 2023
-
Abstract
- We have synthesized a novel bronsted acidic surfactant, 3-methyl-1-sulfonic acid imidazolium dioctyl sulfosuccinate [MSIM]<superscript>+</superscript> [DOSS]<superscript>−</superscript>. We explored catalytic activity of [MSIM]<superscript>+</superscript> [DOSS]<superscript>−</superscript> for regioselective synthesis of novel class of thiazolotriazolones from the reaction of aldehydes/ketones, thiosemicarbazide and ethylbromo acetate in aqueous medium at room temperature. The regio-selectivity was confirmed by DFT and IR frequency calculations. The present methodology offers a feasible approach for swift access to collection of extremely pure products with wide substrate scope having several advantages such as excellent yields, short reaction time, easy work-up procedure for isolation of product and use of surfactant as eco-friendly catalyst, use of water as an universal solvent and novelty in synthesis of surfactant [MSIM]<superscript>+</superscript> [DOSS]<superscript>−</superscript> as well as investigation of regioselective synthesis of novel class of thiazolotriazolones. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10406638
- Volume :
- 43
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- Polycyclic Aromatic Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 169784417
- Full Text :
- https://doi.org/10.1080/10406638.2022.2118327