Modelling of polymerization kinetics and molar mass development in the nitroxide‐mediated polymerization (NMP) of styrene in supercritical carbon dioxide using the PC‐SAFT equation of state.

A mathematical model for polymerization kinetics and molar mass development in the nitroxide‐mediated polymerization (NMP) of vinyl monomers in supercritical carbon dioxide (scCO2) has been developed. The method of moments is used for molar mass development. The perturbed‐chain statistical associating fluid theory (PC‐SAFT) equation of state is used to estimate the number of stable phases present at equilibrium in the reaction mixture, critical number average chain length at which polymer particles are formed, and monomer concentration in each phase. Pure and binary PC‐SAFT interaction parameters are estimated from liquid–liquid equilibrium (LLE) and liquid–vapour equilibrium (LVE) experimental data at 60 to 129°C. The effect of pressure on monomer conversion and molar mass development in the polymerization of styrene (Sty) using benzoyl peroxide (BPO) and 2,2,6,6‐Tetramethylpiperidinyl‐1‐oxyl (TEMPO) at 120°C and 300–500 bar is studied. It was observed that increasing pressure increases polymerization rate without significantly affecting molar mass development. [ABSTRACT FROM AUTHOR]