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Electrochemically Mediated Fixation of CO2: Synthesis of Functionalized Oxazolidine‐2,4‐Diones by Three‐Component Reactions.
- Source :
- Advanced Synthesis & Catalysis; 7/4/2023, Vol. 365 Issue 13, p2183-2187, 5p
- Publication Year :
- 2023
-
Abstract
- Carbon dioxide is a harmful greenhouse gas, as well as a valuable resource. Here, a three‐component cyclization reaction was developed for the synthesis of oxazolidine‐2,4‐diones by immobilizing CO2 under the electrochemistry and copper catalyst. Propargyl amide was used as the reaction substrate to capture carbon dioxide to produce carboxyl anion, while selenide produced electrophilic receptor to activate the triple bond under electrochemical conditions. Then, intramolecular cyclization reaction was carried out to obtain the target product. Through this environmentally friendly strategy, a series of important oxazolidine‐2,4‐diones was synthesized. [ABSTRACT FROM AUTHOR]
- Subjects :
- CARBON sequestration
COPPER catalysts
CARBON dioxide
GREENHOUSE gases
AMIDES
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 365
- Issue :
- 13
- Database :
- Complementary Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 164876489
- Full Text :
- https://doi.org/10.1002/adsc.202300396