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Designing a Length‐Modulated Azide Photocrosslinker to Improve the Stretchability of Semiconducting Polymers.

Authors :
Kim, Seung Hyun
Chung, Sein
Kim, Minkyu
Yoo, Dongho
Ok, Eunsol
Kim, Seunghyun
Song, Kyu Chan
Song, Young Jae
Kang, Boseok
Cho, Kilwon
Source :
Advanced Functional Materials; 6/2/2023, Vol. 33 Issue 23, p1-13, 13p
Publication Year :
2023

Abstract

To impart high stretchability to semiconducting polymers, researchers have used a photocrosslinking approach based on the nitrene chemistry of an azide‐incorporated molecular additive. However, understanding of the molecular design of azide crosslinkers with respect to their effects on the electrical and mechanical properties of semiconducting polymer thin films is lacking. In this study, the effects of an azide photocrosslinker's molecular length and structure on the microstructural, electrical features, and stretchability of photocrosslinked conjugated polymer films is investigated. For a systematic comparison, a series of nitrene‐induced photocrosslinkers (n‐NIPSs) with different numbers of ethylene glycol repeating units (n = 1, 4, 8, 13) that bridge two tetrafluoro‐aryl azide end groups is synthesized. Two semicrystalline conjugated polymers and two nearly amorphous conjugated polymers are co‐processed with n‐NIPSs and crosslinked by brief exposure to UV light. It is found that, among the synthesized n‐NIPSs, the shortest one (1‐NIPS) is the most efficient in improving the stretchability of crosslinked indacenodithiophene‐benzothiadiazole films and that the improvement is achieved only with nearly amorphous polymers, not with semicrystalline conjugated polymers. On the basis of systematic studies, it is suggested that crosslinking density in amorphous regions is important in improving thin film stretchability. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
1616301X
Volume :
33
Issue :
23
Database :
Complementary Index
Journal :
Advanced Functional Materials
Publication Type :
Academic Journal
Accession number :
164095432
Full Text :
https://doi.org/10.1002/adfm.202212127