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Paddle‐Wheel Dirhodium Complexes Bearing Bulky Carboxylate Ligands: Synthesis and Catalysis in Carbene Insertion Reactions.
- Source :
- Chemistry - An Asian Journal; Jun2023, Vol. 18 Issue 11, p1-5, 5p
- Publication Year :
- 2023
-
Abstract
- Dirhodium complexes bearing bulky carboxylate ligands are synthesized and characterized. The steric bulk of carboxylate ligands could affect the reaction selectivity in Rh‐catalyzed intramolecular reactions: Rh catalysts with bulky carboxylate ligands provided five‐membered ring products preferentially via the insertion into a carbon–hydrogen bond. Meanwhile, six‐membered ring products were obtained using conventional Rh catalysts via the insertion of a carbon‐carbon double bond. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18614728
- Volume :
- 18
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Chemistry - An Asian Journal
- Publication Type :
- Academic Journal
- Accession number :
- 164064054
- Full Text :
- https://doi.org/10.1002/asia.202300223