Removal of Pb(II) by Adsorption of HCO–(Fe 3 O 4) x Composite Adsorbent: Efficacy and Mechanism.

With the development of industry, the concentration of lead (Pb) in water bodies is gradually increasing, the forms of Pb pollution in water are becoming increasingly diversified, and the environmental and human health hazards caused by Pb pollution are receiving increasing attention. A HCO–(Fe₃O₄)_x composite adsorbent prepared by the coprecipitation method of Fe₃O₄ mixed in cerium-rich grinding and polishing sludge was used to remove Pb from water. The effects of Ce/Fe molar ratio, pH, dosing amount, and time on the adsorption of HCO–(Fe₃O₄)_x for Pb removal were investigated and the adsorption isotherm model, adsorption kinetics, and adsorption mechanism were studied. The results showed that the maximum adsorption capacity of HCO–(Fe₃O₄)_x on Pb(II) was 35.93 mg·g⁻¹ at a Ce/Fe molar ratio of 1.5:1, pH 4–5, and temperature of 25 °C, and the removal rate could reach 96.05%; the process of Pb(II) adsorption by HCO–(Fe₃O₄)_x was in accordance with the Langmuir isothermal adsorption model and the pseudo-second-order reaction kinetic model; chemisorption was dominant. Characterization results, such as EDS, XRD, and XPS, showed that the composite preparation of HCO with Fe₃O₄ increased the specific surface area of HCO–(Fe₃O₄)_x and generated amorphous iron oxides, such as FeCe₂O₄, FeOOH, Fe₃O₄, and Fe₂O₃, which provided conditions for the formation of Fe-O-Pb and Ce-O-Pb complexes during the adsorption process, thus facilitating the adsorption removal of Pb(II). [ABSTRACT FROM AUTHOR]