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B(3,4,5-F3H2C6)3 Lewis acid-catalysed C3-allylation of indoles.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 4/28/2023, Vol. 52 Issue 16, p5039-5043, 5p
- Publication Year :
- 2023
-
Abstract
- Herein we report the B(3,4,5-F<subscript>3</subscript>H<subscript>2</subscript>C<subscript>6</subscript>)<subscript>3</subscript>-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies. [ABSTRACT FROM AUTHOR]
- Subjects :
- INDOLE compounds
DENSITY functional theory
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 52
- Issue :
- 16
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 163312749
- Full Text :
- https://doi.org/10.1039/d3dt00745f