Back to Search
Start Over
Oxalate-assisted assembly of two polyoxotantalate supramolecular frameworks with proton conduction properties.
- Source :
- Chemical Communications; 3/28/2023, Vol. 59 Issue 25, p3735-3738, 4p
- Publication Year :
- 2023
-
Abstract
- An oxalate-assisted strategy was first developed for creating new polyoxotantalates (POTas). With this strategy, two brand-new POTa supramolecular frameworks based on uncommon dimeric POTa secondary building units (SBUs) were constructed and characterized. Interestingly, the oxalate ligand can not only serve as a coordination ligand to form unique POTa SBUs but also act as a key hydrogen bond acceptor to construct supramolecular architectures. Besides, the architectures show outstanding proton conductivity. The strategy opens up new opportunities for developing new POTa materials. [ABSTRACT FROM AUTHOR]
- Subjects :
- PROTON conductivity
OXALATES
HYDROGEN bonding
PROTONS
ATOMS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 59
- Issue :
- 25
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 162632255
- Full Text :
- https://doi.org/10.1039/d2cc07027h