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Aqua(2,2'-bi-1H-imidazole)chloro-copper(II) chloro(iminodiacetato)-copper(II) monohydrate.
- Source :
- Acta Crystallographica: Section C (Wiley-Blackwell); Jan2005, Vol. 61 Issue 1, pm10-m12, 3p, 2 Diagrams, 2 Charts
- Publication Year :
- 2005
-
Abstract
- In the title compound, [CuCl(C<subscript>6</subscript>H<subscript>6</subscript>N<subscript>4</subscript>)(H<subscript>2</subscript>O)][Cu(C<subscript>4</subscript>H<subscript>5</subscript>NO4<subscript>)</subscript>Cl]·H<subscript>2</subscript>O, the Cu<superscript>II</superscript> atom in the cation is coordinated by one Cl<superscript>-</superscript> ion, two N atoms of the 2,2'-biimidazole ligand and one aqua ligand. Within the anion, the Cu<superscript>II</superscript> atom is bonded to one Cl<superscript>-</superscript> ion, and one N and two O atoms of the iminodiacetate ligand. Neighbouring cations and anions are connected to each other by Cu···Cl semi-coordination bonds of 2.830 (12) and 3.071 (12) baring;, forming a Cu<subscript>2</subscript>Cl<subscript>2</subscript> rectangular unit. The dinuclear units further link into a polymeric chain along the a axis through Cu···O<subscript>aqua</subscript> interactions of 2.725 (3) baring;. Including the long coordination bonds, the geometries around the Cu atoms in the cation and anion are square-pyramidal and distorted octahedral, respectively. [ABSTRACT FROM AUTHOR]
- Subjects :
- IMIDAZOLES
COPPER compounds
ATOMS
CATIONS
LIGANDS (Chemistry)
CRYSTALLOGRAPHY
Subjects
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 61
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 16175271
- Full Text :
- https://doi.org/10.1107/S0108270104028732