Extraction of silica from fly-ash and fabrication of silica-clay composite for dye removal and kinetic studies.

A facile and green approach to extract silica from the coal fly-ash waste is extremely critical for environmental sustainability and economically suitable. In this study, we have used acid-alkali coupled approach to improvised the proficiency of the extraction process. The sodium hydroxide (NaOH) soaking results the formation of the sodium silicate (Na₂SiO₃) solution then pure silica was obtained by heating at high temperature; this coupled route-way results better yield of silica (SiO₂) which is ∼ 40 g. The efficiency of pure silica is not enough to remove toxic effluents from the aqueous media. A highly versatile approach of composite formation was adopted to fabricate silica-clay composite using kaolinite-clay and extracted silica. Both materials, extracted silica and its silica-clay composite were analyzed using scanning electron microscopy (SEM), energy dispersive X-ray (EDX) method, X-ray diffraction technique (XRD) and Fourier transform infra-red spectroscopy (FTIR). The silica-clay composite showed plate-tubular like morphology with enormous binding sites available for the sorption pollutants like organic dyes. It has shown excellent sorption of methylene blue (MB) efficiency of 131.5 mg/g, while silica furnished the sorption of 70.5 mg/g. Results revealed that the synthesized material could probably have better potential for dye removal from industrial effluents. [ABSTRACT FROM AUTHOR]