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Co‐Intercalation of Dual Charge Carriers in Metal‐Ion‐Confining Layered Vanadium Oxide Nanobelts for Aqueous Zinc‐Ion Batteries.
- Source :
- Angewandte Chemie International Edition; 1/26/2023, Vol. 62 Issue 5, p1-8, 8p
- Publication Year :
- 2023
-
Abstract
- Vanadium‐based oxides with high theoretical specific capacities and open crystal structures are promising cathodes for aqueous zinc‐ion batteries (AZIBs). In this work, the confined synthesis can insert metal ions into the interlayer spacing of layered vanadium oxide nanobelts without changing the original morphology. Furthermore, we obtain a series of nanomaterials based on metal‐confined nanobelts, and describe the effect of interlayer spacing on the electrochemical performance. The electrochemical properties of the obtained Al2.65V6O13 ⋅ 2.07H2O as cathodes for AZIBs are remarkably improved with a high initial capacity of 571.7 mAh ⋅ g−1 at 1.0 A g−1. Even at a high current density of 5.0 A g−1, the initial capacity can still reach 205.7 mAh g−1, with a high capacity retention of 89.2 % after 2000 cycles. This study demonstrates that nanobelts confined with metal ions can significantly improve energy storage applications, revealing new avenues for enhancing the electrochemical performance of AZIBs. [ABSTRACT FROM AUTHOR]
- Subjects :
- VANADIUM oxide
NANOBELTS
CHARGE carriers
METAL ions
ENERGY storage
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 62
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 161471328
- Full Text :
- https://doi.org/10.1002/anie.202216089