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Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate.

Authors :
Chidambaranathan, Balasubramanian
Sivaraj, Settu
Selvakumar, Shanmugam
Source :
Acta Crystallographica Section E: Crystallographic Communications; Jan2023, Vol. 79 Issue 1, p8-13, 11p
Publication Year :
2023

Abstract

The title compound, C<subscript>6</subscript>H<subscript>15</subscript>N<subscript>2</subscript>O<superscript>+</superscript>·C<subscript>6</subscript>H<subscript>2</subscript>N<subscript>3</subscript>O<subscript>7</subscript><superscript>-</superscript>·H<subscript>2</subscript>O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C<subscript>6</subscript>H<subscript>15</subscript>N<subscript>2</subscript>O)<superscript>+</superscript>, one anion (C<subscript>6</subscript>H<subscript>2</subscript>N<subscript>3</subscript>O<subscript>7</subscript>)<superscript>-</superscript> and a water molecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C--H...O, O--H...O, O--H...N and N--H...O hydrogen-bonding interactions and π-π stacking. The intermolecular interactions of the synthesized compound were quantified by Hirshfeld surface analysis. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
20569890
Volume :
79
Issue :
1
Database :
Complementary Index
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
161167936
Full Text :
https://doi.org/10.1107/S2056989022011409