Sweet, Sugar-Coated Hierarchical Platinum Nanostructures for Easy Support, Heterogenization and Separation.

Metal nanoparticles are increasingly gaining interest in the field of heterogeneous catalysis. Here, we present a novel strategy for synthesizing sugar-coated platinum nanostructures (SC-Pt-NS) from the carbohydrates sucrose and D(-)-fructose. In the synthesis from a mixture of H₂PtCl₆·6H₂O, the carbohydrate in an ionic liquid (IL) yielded primary particles of a homogeneous average size of ~10 nm, which were aggregated to hierarchical Pt nanostructures of ~40–65 nm and surrounded or supported by the carbohydrate. These sugar-coated platinum nanostructures present a facile way to support and heterogenize nanoparticles, avoid leaching and enable easier separation and handling. The catalytic activity of the SC-Pt-NS was shown in the hydrosilylation test reaction of phenylacetylene with triethylsilane, where very high turnover frequency (TOF) values of up to 87,200 h⁻¹ could be achieved, while the platinum metal leaching into the product was very low. [ABSTRACT FROM AUTHOR]