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Biintercalate formed on the basis of 2D semiconductor matrix, ferroelectric and ferromagnetic phases.

Authors :
Maksymych, Vitalii
Calus, Dariusz
Klapchuk, Myroslava
Shvets, Roman
Chabecki, Piotr
Kohut, Zenoviy
Ivashchyshyn, Fedir
Source :
Molecular Crystals & Liquid Crystals; 2022, Vol. 748 Issue 1, p122-133, 12p
Publication Year :
2022

Abstract

The paper presents the structural-energy, electrically conductive and polarization properties of biintercalant clathrate GaSe≪NaNO<subscript>2</subscript>> +<FeCl<subscript>3</subscript>≫. The existence of two modifications of the crystal structure with interplanar distances c<subscript>1</subscript> = 16.072 Å and c<subscript>2</subscript> = 15.977 Å was established by X-ray diffractometry. The сurrent-voltage characteristics of the biitercalant clathrate GaSe≪NaNO<subscript>2</subscript>> +<FeCl<subscript>3</subscript>≫ acquires a hysteresis form, which indicates the accumulation of electric charge at the interfacial boundaries. The spectrum of impurity energy levels was established by the method of thermally stimulated discharge with short-circuited contacts in the temperature range from 240 to 340 K, which testifies to the relaxation of the hetero-charge and the quasi-continuity of energy states. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15421406
Volume :
748
Issue :
1
Database :
Complementary Index
Journal :
Molecular Crystals & Liquid Crystals
Publication Type :
Academic Journal
Accession number :
160350680
Full Text :
https://doi.org/10.1080/15421406.2022.2067667