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Electronic Structure, Optical and Magnetic Properties of Oxygen-Deficient Gray TiO 2–δ (B).
- Source :
- Inorganics; Nov2022, Vol. 10 Issue 11, p184, 10p
- Publication Year :
- 2022
-
Abstract
- The gray-colored oxygen-deficient TiO<subscript>2–δ</subscript>(B) nanobelts have been synthesized through a combination of the hydrothermal method followed by an ion exchange process and vacuum annealing. Electron paramagnetic resonance reveals an existence of F-centers in the form of electron-trapped oxygen vacancies within the anionic sublattice of the gray bronze TiO<subscript>2</subscript> that induces its colouration. The diffuse reflectance spectroscopy showed that the formation of oxygen vacancies into TiO<subscript>2</subscript>(B) significantly increases its absorption intensity in both visible and near infrared ranges. The band gap of TiO<subscript>2</subscript>(B) with anionic defects is equal to 3.03 eV (against 3.24 eV for white TiO<subscript>2</subscript>(B) treated in air). Room temperature ferromagnetism associated with the defects was detected in gray TiO<subscript>2–δ</subscript>(B), thus indicating it belongs it to the class of dilute magnetic oxide semiconductors. It was found that in the low-temperature range (4 K), the magnetic properties of vacuum annealed TiO<subscript>2</subscript>(B) do not differ from those for TiO<subscript>2</subscript>(B) treated in air. We hope that the findings are defined here make a contribution to further progress in fabrication and manufacturing of defective TiO<subscript>2</subscript>-based nanomaterials for catalysis, magnetic applications, batteries, etc. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 23046740
- Volume :
- 10
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Inorganics
- Publication Type :
- Academic Journal
- Accession number :
- 160231181
- Full Text :
- https://doi.org/10.3390/inorganics10110184