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The 5.8 µm absorption bands for nitric acid (H14N16O3): line positions and intensities for the ν2 band at 1709.567 cm−1 and for its first associated hot bands (ν2+ν9−ν9, ν2+ν7−ν7, ν2+ν6−ν6)

Authors :
Perrin, A.
Manceron, L.
Armante, R.
Kwabia-Tchana, F.
Roy, P.
Doizi, D.
Toon, G.C.
Source :
Molecular Physics; Aug2022, Vol. 120 Issue 15/16, p1-17, 17p
Publication Year :
2022

Abstract

This paper is the second of two back-to-back works, whose goal was to generate a more accurate linelist for the 5.8 µm absorption band of HNO<subscript>3</subscript>. Here, we report improved line positions and intensities in the ν<subscript>2</subscript> cold band which is the main band in this region. For this, we recorded four high-resolution Fourier transform spectra for the ν<subscript>2</subscript> band, centered at 1709.567 cm<superscript>−1</superscript>, under different experimental conditions. Using these spectra, a new extended line position analysis was performed for the ν<subscript>2</subscript> band, leading to more accurate line positions. In parallel, individual line intensities were measured. It appears that, although the ν<subscript>2</subscript> band is mainly of B-type, it also possesses a (very) weak A-type component that cannot be ignored. Overall, the line intensities in this new database are about 8% weaker than those quoted presently in the HITRAN () or GEISA () databases. Our final linelist for HNO<subscript>3</subscript> at 5.8 µm is provided as a supplement to this paper. It includes lines from the ν<subscript>2</subscript> band together with those of the ν<subscript>2</subscript>+ν<subscript>9</subscript>−ν<subscript>9,</subscript> ν<subscript>2</subscript>+ν<subscript>6</subscript>−ν<subscript>6</subscript>, and ν<subscript>2</subscript>+ν<subscript>7</subscript>−ν<subscript>7</subscript> associated hot bands that were generated during the first part of this study, described in the companion paper. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00268976
Volume :
120
Issue :
15/16
Database :
Complementary Index
Journal :
Molecular Physics
Publication Type :
Academic Journal
Accession number :
160114034
Full Text :
https://doi.org/10.1080/00268976.2021.1998931