Interfacial-engineered CoTiO3-based composite for photocatalytic applications: a review.

Photocatalysis is a green chemical process that could partly solve energy and pollution issues. Catalysts such as cobalt titanate, CoTiO₃, have intrigued scientists due to a visible light-responsive band gap of about 2.3 eV and a high valance band potential of about 2.35 eV that allow a remarkable oxidative activity. Nonetheless, CoTiO₃ photocatalytic activity is limited by charge recombination, thus requiring modifications. For instance, the introduction of a second semiconductor allows improved charge separation and notable enhancement of the activity. Here we review interfacial engineering of CoTiO₃ by introduction of a second semiconductor. We describe the synthesis and photocatalytic applications of bare and modified CoTiO₃. Modified CoTiO₃ composites are categorized into Type-I, Type-II, Z-scheme, and S-scheme heterojunctions, depending on the band structures of the composite. [ABSTRACT FROM AUTHOR]