Petrogenesis and tectonic setting of Early Silurian island-arc-type quartz diorite at the southern margin of the East Kunlun orogenic belt: analysis of the evolution of the Proto-Tethyan Ocean.

The subduction of the Proto-Tethyan Ocean is still a controversial subject. Here we report zircon U-Pb ages, geochemistry, and Hf isotopic compositions of the zircon in the Mengkete quartz diorite in the Buqingshan–A'nyemaqen Tectonic Mélange Belt, which lies at the southern margin of the East Kunlun orogenic belt on the northern Tibetan Plateau, to constrain the petrogenesis of subduction-related granitoids and to reconstruct the evolution of the Buqingshan–A'nyemaqen Ocean. Zircons U-Pb dating yields coeval ages of 441–436 Ma for Mengkete quartz diorite. Mengkete plutons have variable SiO₂ (56.63–65.22%) and high Al₂O₃ (16.09–17.79%) contents and aluminous saturation indexes (A/CNK ratios) ranging from 0.77 to 0.96, which define their metaluminous and medium-K₂O calc-alkaline signatures. The plutons have a low total rare-earth element (REE) content (45.49–168.31 ppm) and slightly positive Eu anomalies (Eu/Eu* in the range of 0.96 to 1.32). They are also enriched in large-ion lithophile elements (LILEs), such as Rb, Th, and Ba, but are depleted in high-field-strength elements (HFSEs), such as Nb, Ta, Zr, Hf, and Ti. Their zircon ε_Hf(t) values ranging from 7.79 to 13.02, and the two-stage Hf (T_DM2) model ages are in the range of 1130–657 Ma. These geochemical signatures indicate that the Mengkete quartz diorite was derived from partial melting of the mafic Meso-Neoproterozoic lower crust during the northward subduction of the Proto-Tethyan Ocean. The evolution of the East Kunlun Belt can be divided into five stages from the Neoproterozoic to late Middle Triassic: (1) an opend Buqingshan‒A'nyemaqen ocean during the Neoproterozoic up to 516Ma; (2) the continuous expansion of the Buqingshan‒A'nyemaqen ocean during the period 516 to 441Ma, along with the beginning of northward subduction in the Late Cambrian; (3) further subduction from 441 to 400Ma, accompanied by the production of large volumes of arc magmatic rocks; (4) the long period during which the Buqinshan–A'nyemaqen Ocean existed (400–240 Ma); and (5) the final closure of the Buqinshan–A'nyemaqen Ocean in the late Middle Triassic. [ABSTRACT FROM AUTHOR]