Insights into the thermal decomposition of organometallic compound ferrocene carboxaldehyde as precursor for hematite nanoparticles synthesis.

The paper deals with the thermal decomposition of organometallic compound ferrocene carboxaldehyde [(C₅H₄CHO)Fe(C₅H₅)] in oxidative atmosphere, which leads to pure hematite nanoparticles, studied with non-isothermal thermogravimetry (TG) protocol. Deconvolution method with Fraser-Suzuki fit function is adopted to resolve the complex multistep TG profiles into six different reaction steps. Step-wise reaction kinetic parameters (activation energy, reaction mechanism function, reaction rate) are estimated based on the mathematical analysis of the multi-heating rate TG data primarily following model-free (integral isoconversional) approach and using master-plot method. The estimated kinetic parameters are utilised to reconstruct the conversion plots which successfully resemble the experimentally observed ones. A plausible reaction process leading to hematite on thermal decomposition of ferrocene carboxaldehyde as the end product is discussed. A comparative discussion on the thermal decomposition of two ferrocene derivatives have been made. The novelty of the present work lies in successful deconvolution of complex TG profiles and hence obtaining the step-wise reaction kinetic parameters demonstrating different reaction mechanisms involved in the thermal synthesis of hematite nanoparticles starting from ferrocene carboxaldehyde which have no prior reporting. Further, a satisfactory agreement between the reconstructed and experimental decomposition profiles establishes the correctness of the applied modelling approach as well as the methodology adopted. [ABSTRACT FROM AUTHOR]