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Crystal structure and Hirshfeld surface analysis of (±)-N′-(2-hydroxy-3-methoxybenzylidene)-2-(4-isobutylphenyl) propionohydrazide.
- Source :
- Acta Crystallographica Section E: Crystallographic Communications; Aug2022, Vol. 78 Issue 8, p860-863, 10p
- Publication Year :
- 2022
-
Abstract
- The title mol­ecule, C<subscript>21</subscript>H<subscript>26</subscript>N<subscript>2</subscript>O<subscript>3</subscript>, adopts a V-shaped conformation and is chiral at the C atom with methyl group attached at the common cut of the edges of the V-conformation and crystallizes as a racemate. It also contains an intra­molecular O--H⋯N hydrogen bond. In the crystal, N--H⋯O hydrogen bonds form chains of mol­ecules extending along the c-axis direction, together with normal van der Waals contacts. The roles of the various inter­molecular inter­actions were clarified by Hirshfeld surface analysis, which reveals that the most important contributions to the crystal packing are from H⋯H (62.6%), C⋯H/H⋯C (15.8%) and O⋯H/H⋯O (15.3%) contacts. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 78
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 158581247
- Full Text :
- https://doi.org/10.1107/S2056989022007605