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Crystal structure and Hirshfeld surface analysis of (±)-N′-(2-hydroxy-3-methoxybenzylidene)-2-(4-isobutylphenyl) propionohydrazide.

Authors :
Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Abdel-Rahman, Laila H.
Abdel-Hameed, Mohamed
Albayati, Mustafa R.
Al-Taif, Elham A.
Source :
Acta Crystallographica Section E: Crystallographic Communications; Aug2022, Vol. 78 Issue 8, p860-863, 10p
Publication Year :
2022

Abstract

The title mol­ecule, C<subscript>21</subscript>H<subscript>26</subscript>N<subscript>2</subscript>O<subscript>3</subscript>, adopts a V-shaped conformation and is chiral at the C atom with methyl group attached at the common cut of the edges of the V-conformation and crystallizes as a racemate. It also contains an intra­molecular O--H⋯N hydrogen bond. In the crystal, N--H⋯O hydrogen bonds form chains of mol­ecules extending along the c-axis direction, together with normal van der Waals contacts. The roles of the various inter­molecular inter­actions were clarified by Hirshfeld surface analysis, which reveals that the most important contributions to the crystal packing are from H⋯H (62.6%), C⋯H/H⋯C (15.8%) and O⋯H/H⋯O (15.3%) contacts. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
20569890
Volume :
78
Issue :
8
Database :
Complementary Index
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
158581247
Full Text :
https://doi.org/10.1107/S2056989022007605