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Crystal structure and Hirshfeld surface analysis of ethyl (3E)-5-(4-chlorophenyl)-3-{[(4-chlorophenyl) formamido]imino}-7-methyl-2H,3H,5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate.
- Source :
- Acta Crystallographica Section E: Crystallographic Communications; Aug2022, Vol. 78 Issue 8, p846-850, 12p
- Publication Year :
- 2022
-
Abstract
- In the title mol­ecule, C<subscript>23</subscript>H<subscript>20</subscript>C<subscript>l2</subscript>N<subscript>4</subscript>O<subscript>3</subscript>S, the thia­zole ring is planar while the pyrimidine unit fused to it adopts a screw-boat conformation. In the crystal, thick sheets parallel to the bc plane are formed by N--H⋯N, C--H⋯N and C--H⋯O hydrogen bonds together with π-π inter­actions between the formamido carbonyl groups and the thia­zole rings. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (30.9%), Cl⋯H/H⋯Cl (20.7%), C⋯H/H⋯C (16.8%) and O⋯H/H⋯O (11.4%) inter­actions. [ABSTRACT FROM AUTHOR]
- Subjects :
- SURFACE analysis
CRYSTAL structure
SURFACE structure
HYDROGEN bonding
CARBONYL group
Subjects
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 78
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 158581244
- Full Text :
- https://doi.org/10.1107/S205698902200603X