Back to Search Start Over

A density scaling conjecture for aging glasses.

Authors :
Niss, Kristine
Source :
Journal of Chemical Physics; 8/7/2022, Vol. 157 Issue 5, p1-8, 8p
Publication Year :
2022

Abstract

The aging rate of glasses has traditionally been modeled as a function of temperature, T, and fictive temperature, while density, ρ, is not explicitly included as a parameter. However, this description does not naturally connect to the modern understanding of what governs the relaxation rate in equilibrium. In equilibrium, it is well known that the relaxation rate, γ<subscript>eq</subscript>, depends on temperature and density. In addition, a large class of systems obeys density scaling, which means the rate specifically depends on the scaling parameter, Γ = e(ρ)/T, where e(ρ) is a system specific function. This paper presents a generalization of the fictive temperature concept in terms of a fictive scaling parameter, Γ<subscript>fic</subscript>, and a density scaling conjecture for aging glasses in which the aging rate depends on Γ and Γ<subscript>fic</subscript>. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
LOGICAL prediction
DENSITY

Details

Language :
English
ISSN :
00219606
Volume :
157
Issue :
5
Database :
Complementary Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
158381866
Full Text :
https://doi.org/10.1063/5.0090869