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Hydrogenation of furfural over Pd@ZIF-67 derived catalysts: direct hydrogenation and transfer hydrogenation.
- Source :
- New Journal of Chemistry; 7/28/2022, Vol. 46 Issue 28, p13715-13724, 10p
- Publication Year :
- 2022
-
Abstract
- Pd particles coated with ZIF-67 (Pd@ZIF-67) was prepared from the self-reduction of palladium acetate. With isopropanol as the solvent, the furfural hydrogenation reaction performances of Pd@ZIF-67 and ZIF-67 heated at different temperatures were tested in H<subscript>2</subscript> and N<subscript>2</subscript> reaction atmosphere, respectively. The pyrolytic carbonization of Pd@ZIF-67 and ZIF-67 produced Pd–Co@C and Co@C in carbon coating structures, respectively. It was found that furfural hydrogenation reaction systems with different catalytic active sites included direct hydrogenation with H<subscript>2</subscript> as the hydrogen source, and transfer hydrogenation with isopropanol as the hydrogen donor. The Pd–Co@C and Co@C with metal active sites both experienced direct hydrogenation and transfer hydrogenation simultaneously, and the direct hydrogenation activity was higher. The ZIF-67 with Lewis acidic sites experienced transfer hydrogenation, and the catalytic activity was higher than the transfer hydrogenation activity of Pd–Co@C and Co@C. Moreover, reaction routes in which furfural direct hydrogenation and transfer hydrogenation occurred in metal active sites and Lewis acidic sites were identified. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 46
- Issue :
- 28
- Database :
- Complementary Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 158059677
- Full Text :
- https://doi.org/10.1039/d2nj01565j