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Unusual Catalytic Effect of Fe 3+ on 2,4-dichlorophenoxyacetic Acid Degradation by Radio Frequency Discharge in Aqueous Solution.
- Source :
- Water (20734441); Jun2022, Vol. 14 Issue 11, p1719-1719, 18p
- Publication Year :
- 2022
-
Abstract
- 2,4-dichlorophenoxyacetic acid (2,4-D) is a widely used herbicide for controlling broad-leaved weeds. The development of an efficient process for treating the refractory 2,4-D wastewater is necessary. In this study, liquid-phase degradation of 2,4-D induced by radio frequency discharge (RFD) was studied. Experimental results showed that the degradation was more effective in acidic than in neutral or alkaline solutions. During the degradation, a large amount of hydrogen peroxide (H<subscript>2</subscript>O<subscript>2,</subscript> 1.2 mM/min, almost equal to that without 2,4-D) was simultaneously produced, and catalytic effects of both ferric (Fe<superscript>3+</superscript>) and ferrous (Fe<superscript>2+</superscript>) ions on the degradation were examined and compared. It was found that 2,4-D degraded more rapidly in the case of Fe<superscript>3+</superscript> than the that of Fe<superscript>2+</superscript>. Such a scenario is explained that Fe<superscript>3+</superscript> was successively reduced to Fe<superscript>2+</superscript> by the atomic hydrogen (•H) and •OH-adducts of 2,4-D resulting from RFD, which in turn catalyzed the H<subscript>2</subscript>O<subscript>2</subscript> to form more •OH radicals through Fenton's reaction, indicating that Fe<superscript>3+</superscript> not only accelerates the degradation rate but also increases the amount of •OH available for 2,4-D degradation by suppressing the back reaction between the •H and •OH. 2,4-dichlorophenol, 4,6-dichlororesorcinol, 2-hydroxy-4-chloro- and 2-chloro-4-hydroxy- phenoxyacetic acids, hydroxylated 2,4-Ds, and carboxylic acids (glycolic, formic and oxalic) were identified as the byproducts. Energy yields of RFD have been compared with those of other nonthermal plasma processes. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20734441
- Volume :
- 14
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Water (20734441)
- Publication Type :
- Academic Journal
- Accession number :
- 157371590
- Full Text :
- https://doi.org/10.3390/w14111719