Back to Search
Start Over
Synthesis, Crystal Structure and Characterization of Two Cobalt (II) Complexes Based on Pyridine Carboxylic Acid Ligands.
- Source :
- Zeitschrift für Anorganische und Allgemeine Chemie; 5/13/2022, Vol. 648 Issue 9, p1-6, 6p
- Publication Year :
- 2022
-
Abstract
- Two undocumented cobalt (II) complexes [Co(5‐Br‐2,3‐pydc)(H2O)3 ⋅ H2O]n (namely Co‐MOF 1) and [Co(6‐Me‐2,3‐pydc)(H2O)3]n (namely Co‐MOF 2), were successfully synthesized by solvothermal method. The X‐ray single crystal diffraction, infrared spectrometer (IR), UV‐Vis spectrum and X‐ray diffraction were used to characterize and analyze the structure of the two MOFs. The single crystal structure analysis showed that Co‐MOF 1 reconnected by Co−N bond and Co−O bond to form a one‐dimensional chains. The Co‐MOF 2 was connected by Co−O and Co−N bonds to form a one‐dimensional chain.The results indicated that complexes Co‐MOF 1 and Co‐MOF 2 have a certain thermal stability and fluorescence properties. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00442313
- Volume :
- 648
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Zeitschrift für Anorganische und Allgemeine Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 157058578
- Full Text :
- https://doi.org/10.1002/zaac.202000418