Catalytically efficient Ni-NiOx-Y2O3 interface for medium temperature water-gas shift reaction.

The metal-support interfaces between metals and oxide supports have long been studied in catalytic applications, thanks to their significance in structural stability and efficient catalytic activity. The metal-rare earth oxide interface is particularly interesting because these early transition cations have high electrophilicity, and therefore good binding strength with Lewis basic molecules, such as H₂O. Based on this feature, here we design a highly efficient composite Ni-Y₂O₃ catalyst, which forms abundant active Ni-NiO_x-Y₂O₃ interfaces under the water-gas shift (WGS) reaction condition, achieving 140.6 μmol_CO g_cat⁻¹ s⁻¹ rate at 300 °C, which is the highest activity for Ni-based catalysts. A combination of theory and ex/in situ experimental study suggests that Y₂O₃ helps H₂O dissociation at the Ni-NiO_x-Y₂O₃ interfaces, promoting this rate limiting step in the WGS reaction. Construction of such new interfacial structure for molecules activation holds great promise in many catalytic systems. Developing effective and stable catalytic interfaces in the medium temperature region is a practical route to replace the existing water gas shift (WGS) process. Here the authors designed a composite Ni-Y₂O₃ catalyst achieving the highest WGS activity for Ni based catalysts. [ABSTRACT FROM AUTHOR]