Streamline Sulfur Redox Reactions to Achieve Efficient Room‐Temperature Sodium–Sulfur Batteries.

It is vital to dynamically regulate S activity to achieve efficient and stable room‐temperature sodium–sulfur (RT/Na−S) batteries. Herein, we report using cobalt sulfide as an electron reservoir to enhance the activity of sulfur cathodes, and simultaneously combining with cobalt single atoms as double‐end binding sites for a stable S conversion process. The rationally constructed CoS2 electron reservoir enables the straight reduction of S to short‐chain sodium polysulfides (Na2S4) via a streamlined redox path through electron transfer. Meanwhile, cobalt single atoms synergistically work with the electron reservoir to reinforce the streamlined redox path, which immobilize in situ formed long‐chain products and catalyze their conversion, thus realizing high S utilization and sustainable cycling stability. The as‐developed sulfur cathodes exhibit a superior rate performance of 443 mAh g−1 at 5 A g−1 with a high cycling capacity retention of 80 % after 5000 cycles at 5 A g−1. [ABSTRACT FROM AUTHOR]