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Two high-nuclearity isopolyoxoniobates containing {Nb54 O151}-based helical nanotubes for the decomposition of chemical warfare agent simulants.
- Source :
- Chemical Communications; 3/11/2022, Vol. 58 Issue 20, p3322-3325, 4p
- Publication Year :
- 2022
-
Abstract
- Two inorganic–organic hybrid isopolyoxoniobates (1 and 2) based on new high-nuclearity {Nb<subscript>54</subscript>O<subscript>151</subscript>} clusters have been synthesized under hydrothermal conditions. In particular, the combination of the unique {Nb<subscript>54</subscript>O<subscript>151</subscript>} clusters with copper-amine complexes has led to rare helical nanotubes, which are further linked by alkali metal cations or copper-amine complexes into two 2D similar bamboo-raft-like layered networks (1 and 2), respectively. Compound 1 exhibits effective base-catalytic decomposition of chemical warfare agent simulants dimethyl methylphosphonate (DMMP) and diethyl cyanophosphonate (DECP). [ABSTRACT FROM AUTHOR]
- Subjects :
- CHEMICAL warfare agents
CHEMICAL decomposition
NANOTUBES
DIMETHYL methylphosphonate
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 58
- Issue :
- 20
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 155619991
- Full Text :
- https://doi.org/10.1039/d1cc06878d