Tribological Properties of the Nanoscale Spherical Y 2 O 3 Particles as Lubricant Additives in Automotive Application.

The continuous tribological development of engine lubricants is becoming more and more vital due to its fuel efficiency improvement and lifetime increasing potential. The antiwear additives play a high role in the lubricants to protect the contacting surfaces even in the presence of thinner oil film. Nanoscale spherical particles in the lubricant may increase the necessary protecting effect. This paper presents the results of the experimental tribological investigation of nanoscale spherical Y₂O₃ (yttria) ceramic particles as an engine lubricant additive. The ball-on-disc tribological measurements have revealed an optimum concentration at 0.5 wt% with about 45% wear scar diameter and 90% wear volume decrease, compared to the reference, neat Group III base oil. The high-magnitude SEM analysis revealed the working mechanisms of yttria: the particles collected in the roughness valleys resulted in a smoother contacting surface, they were tribo-sintered and they have also caused slight plastic deformation of the outer layer of the metallic surface. [ABSTRACT FROM AUTHOR]